Here is a look at the xG stats for PSG vs Leipzig in the Champions League on October 19, 2021. Leipzig had more shots, but the quality of PSG’s chances were higher, and the xG is pretty much in line with the final scorer, which finished 3-2 in favour of Paris.
xG PSG 3.05-2.11 RB Leipzig shots map (Actual score Paris 3-2 RBL)
1-0 Mbappe goal xG 0.11
1-1 Silva goal xG 0.49
1-2 Mukiele goal xG 0.58